Contrasting water–rock interaction behaviors of antimony and arsenic in contaminated rivers around an antimony mine,Hunan Province,China     

《Chemie der Erde / Geochemistry》2021,81(2):125748

Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   

鄂尔多斯盆地南部马莲河流域地下水中锶富集特征及成因分析     

李海学  程旭学  马岳昆  刘伟坡  周斌 《现代地质》2021,35(3):682-692

马莲河流域地处鄂尔多斯盆地南部黄土高原区,按储水介质和埋藏条件可将地下水分为黄土潜水、基岩潜水和基岩承压水三类,利用2015—2018年流域的295组地下水水化学数据,分析了地下水中锶(Sr²⁺)的质量浓度水平、垂向分布及沿流向分布的特征,并采用因子相关性研究地下水中Sr²⁺的来源和富集成因。结果表明:马莲河流域地下水富锶现象显著,黄土潜水、基岩潜水和基岩承压水中锶的平均质量浓度分别为1.14 mg/l、1.39 mg/l和5.24 mg/l;地下水中锶富集成因主要是含锶矿物天然状态下的水-岩作用,黄土潜水、基岩潜水和基岩承压水三类地下水中Sr²⁺的主要来源分别为碳酸盐岩与铝硅酸盐岩、碳酸盐岩与硫酸盐和碳酸盐矿物的溶滤作用;地下水中Sr²⁺的质量浓度沿流向呈逐渐增大的趋势,在不同区域中随深度变化的趋势不一致。  相似文献   

Constraints of Mantle and Crustal Sources Interaction during Orogenesis of Pre- and Post-collision Granitoids from the Northern Arabian-Nubian Shield: A Case Study from Wadi El-Akhder Granitoids,Southern Sinai,Egypt     

Moustafa M. MOGAHED  Khaled M. ABDELFADIL 《《地质学报》英文版》2021,95(5):1527-1550

The Egyptian older and younger granitic rocks emplaced during pre- and post-collision stages of Neoproterozoic Pan-African orogeny, respectively, are widely distributed in the southern Sinai Peninsula, constituting 70% of the basement outcrops. The Wadi El-Akhder, southwestern Sinai, is a mountainous terrain exposing two granitoid suites, namely the Wadi El-Akhder Older Granites (AOG) and the Homra Younger Granites (HYG). The AOG (granodiorites with subordinate tonalite compositions) have geochemical characteristics of medium-K calc-alkaline, metaluminous to mildly peraluminous granitoids formed in an island-arc environment, which are conformable with well-known Egyptian older granitoids rocks, whereas the HYG display calc-alkaline to slightly alkaline nature, peraluminous syeno-, monzogranites and alkali feldspar granites matching well those of the Egyptian younger granites. With respect to the AOG granitoids, the HYG granites contain lower Al2O3, FeO*, MgO, MnO, CaO, TiO2, Sr, Ba, and V, but higher Na2O, K2O, Nb, Zr, Th, and Rb. The AOG are generally characterized by enrichment in LILE and LREE and depletion in HFSE relative to N-MORB values (e.g., negative Nb and Ta anomalies). The geochemical features of the AOG follow assimilation-fractional crystallization (AFC) trends indicative of extensive crustal contamination of magma derived from a mantle source. The chemical characteristics of the AOG are remarkably similar to those of subduction-related granitoids from the Arabian-Nubian Shield (ANS). The compositional variations from monzogranites through syenogranites to alkali feldspar granite within HYG could not be explained by fractional crystallization solely. Correlating the whole-rock composition of the HYG to melts generated by experimental dehydration melting of meta-sedimentary and magmatic rocks reveals that they appear to be derived by extended melting of psammitic and pelitic metasediments, which is similar to the most of younger granitic suites in the ANS.  相似文献   

山东省菏泽凸起地热田岩溶地热水水化学水平演化特征   总被引：1，自引：0，他引：1  

史启朋  宋帅良  孟甲  郑慧铭 《中国岩溶》2021,40(2):310-318

在前人研究成果的基础上,选择A-A′和B-B′两条路径,采用Piper三线图解、Schoeller图解、Na－K－Mg平衡图解、饱和指数计算评价等方法,研究山东菏泽凸起地热田地热水沿路径上的循环演化特征。结果表明:沿A-A′、B-B′剖面岩溶冷水→岩溶热水,水化学类型由SO4.HCO3－Ca.Mg.Na或SO4.HCO3－Ca.Mg向SO4－Ca.Na或SO4－Ca演化,矿化度逐渐增大,HCO3-浓度逐渐减少,SO42-、Ca2+、K+浓度逐渐增大,反映出岩溶冷水向岩溶热水演化的补给特征;水化学三线图上岩溶冷水、热水处在不同的区域,显示岩溶冷水向岩溶热水演化补给;距补给区由近到远,水岩作用程度逐步提高,饱和指数逐渐增大,岩溶地热水溶滤作用增强。   相似文献   

Discussion on research advances and hot issues in diagenesis of clastic-rock reservoirs          下载免费PDF全文

Luo Jing-Lan  Li Chi  Lei Chuan  Cao Jiang-Jun  Song Kun-Peng 《古地理学报》2021,22(6):1021-1040

The research on diagenesis of clastic-rock reservoir is developing rapidly in recent ten years. Thus, it is of great significance in academic and scientific exploration to summarize the domestic and international research progress and the key issues of frontier research on diagenesis. The research progress, main achievement and recognition in diagenesis of clastic-rock reservoirs in recent years is discussed, and the hot issues or developing trend of diagenesis in the future is probed in this paper, on the basis of summarizing the previous research results and understanding, combined with the typical research examples at home and abroad. It is believed that great progress was obtained in provenance and parent rock constraints on sandstone types and their diagenetic evolution pathways, impact of fluid-rock interaction and its product on diagenesis, influence of thermodynamics and overpressure background on diagenesis and pore development, the timing sequence between hydrocarbon accumulation and filling process and the sandstone reservoir becoming low permeability-densification. At present, diagenetic research is developing in direction of the spatial and temporal dynamics and quantitative evolution mechanistic and diagenetic system controlled by the basin fluid dynamics, thermal dynamic processes, combining the micro-scale diagenesis research with the basin macroscopic background such as sedimentation from the source to the basin, burial history, hydrocarbon maturity and charge into reservoirs, tectonic evolution and fluid activity, and fluid and rock interaction.The aim of this paper is to induce the academic peers and experts in diagenesis and the related research fields to come forward with their valuable contributions, to cooperate and work together and joint efforts on the research exquisite, profundity and breadth of diagenesis, and application of the most advanced analytical measurement techniques and methods, as well as integration and infiltration of multidisciplinary, in order to promote the course of the clastic-rock reservoir diagenetic research in China.  相似文献   

方解石与含硅流体的水-岩反应实验及其对“硅化碳酸盐岩”储层成因的启示     

杨源显  陈强路  丘靥  尤东华  王小林 《高校地质学报》2021,27(2):218-228

近年来的油气勘探表明, 含硅热液是碳酸盐岩层系中一种重要的溶蚀性流体, 查明其与碳酸盐岩的水-岩反应机理是揭示“硅化碳酸盐岩”储层发育机制并实现储层分布预测的基础和关键问题之一。文章采用熔融毛细硅管和水热反应釜为反应腔,开展了200~375℃范围内方解石和含硅流体的水岩反应实验。利用原位拉曼光谱技术在线描述反应过程中体系组成的变化,对于淬火后的固相样品,则采用扫描电镜—能谱分析进行形貌观测和成分鉴定。首先,查明了含硅流体与方解石脱碳反应发生的温度条件。方解石和含硅流体在275℃以上反应形成CO₂,固相为非硅灰石的钙硅酸盐,其结构有待进一步揭示。该结果表明单纯的硅质组分难以在储层温度条件下与灰岩发生反应;其次,提出高盐度、富CO2流体作用是造成灰岩溶蚀的重要因素;最后, CO₂的存在能够促进硅质（含石英）沉淀。在上述实验认识的基础上,结合前人研究结果探讨了塔里木盆地顺托果勒地区“硅化碳酸盐岩”储层的发育机制。含硅热液沿深大断裂上移,途径震旦系—下奥陶统白云岩层系,其中的硅质组分将与白云石反应形成富镁硅酸盐和CO₂。CO₂是重要的酸性组分,有利于鹰山组碳酸盐的溶蚀和孔隙的保存。流体温度和压力的降低以及CO₂的存在促进了石英沉淀,并形成了大量的石英晶间孔隙。  相似文献   

Response of ocean dynamics to multiple equilibria of the Kuroshio path South of Japan     

《Dynamics of Atmospheres and Oceans》2019

Variability of the Kuroshio path to the south of Japan plays a central role in the local climate change and exerts tremendous influences on the local atmosphere and ocean. In this study, the response of ocean dynamics, in terms of the eddy kinetic energy (EKE), potential vorticity (PV), relative vorticity, and eddy-mean flow interaction, to the Kuroshio path change is discussed. Kuroshio path south of Japan includes the near-shore non-large meander (nNLM), the off-shore non-large meander (oNLM), and the typical large meander (tLM). Analyses reveal that the distribution of EKE, PV, relative vorticity, and energy exchange between the eddy field and the mean flow respectively varies with the Kuroshio path: (1) The tLM has the maximum EKE along the path; (2) The positive and negative PV are located at the onshore and offshore side of Kuroshio axis, respevetively; (3) The distributions of anomalous relative voritcity of nNLM, oNLM, and tLM are consistent with sea surface height anomalies (SSHAs); (4) The tLM has the largest energy exchange between the eddy field and the mean flow in terms of the rate of barotropic energy conversion. On the other hand, the stability analysis of ocean currents suggests that the three Kuroshio paths south of Japan have their own intrinsic properties of the instability.  相似文献   

登陆北上山东台风暴雨非对称分布的成因对比分析          下载免费PDF全文

孙兴池  吴炜  孙莎莎 《山东气象》2019,39(3):55-63

应用常规气象观测资料、NCEP 1°×1°再分析资料,选取登陆北上山东地点相近但暴雨落区分别位于台风中心西北侧和东北侧的两个台风,分析暴雨落区相对台风中心非对称分布的成因。结果表明：台风进入中纬度以后,0421号台风“海马”位于高空深槽前,与西风槽相互作用,西风槽携带的冷空气从西北侧侵入台风环流,产生湿斜压锋区强迫抬升、冷暖空气交绥、水汽辐合等因素造成暴雨,暴雨趋于出现在台风中心的西北侧,为高比湿舌前方、较强水汽辐合区与相当位温密集区叠加的区域;而0509号台风“麦莎”与副热带高压相互作用,引起涡度及涡度平流的非对称改变,暴雨区与500 hPa正涡度区或正涡度平流相对应,暴雨趋于出现在台风中心的东北侧,为强正涡度平流区与水汽辐合叠加的区域。  相似文献   

Household level influences on fragmentation in an African park landscape     

《Applied geography (Sevenoaks, England)》2015

The process of landscape fragmentation outside park borders occurs through the actions of people living near the boundaries. In the Kibale National Park landscape in western Uganda, human-landscape relationships are typified by small-scale subsistence agriculture, in which households rely on resources provided in forests and wetlands, whose use is in turn shaped by perceptions of resource availability. To understand and manage for fragmentation of resource pools, modeling and identifying the proximate drivers, and thus enacted resource extraction and utilization – is of fundamental importance. We combine landscape analysis at the household scale, using remotely sensed data, with household surveys, to understand the potential human drivers of local scale landscape change. We found strong evidence for a local household zone (LHZ) effect on fragmentation patterns with geographical and socioecological heterogeneities in LHZ impact. Differences were influenced by wealth, and in some cases, tribal identity. The perception of crop raiders – primarily baboons and small monkeys, but also elephants and other animals – may have largely shaped human-environment interactions, and were associated with fragmentation. Ninety-two percent of the best fit models included the attitude that the park should stay, but associated it with increased fragmentation, suggesting that the uncharacteristic non-hostile attitude about Kibale does not directly translate into conservation-friendly local human-environment interactions. This study provides insight into park–neighbor interactions and the influence of the LHZ on protected-area landscapes, and it points to important points in the system for collaborative opportunities to engage communities and conservation managers.  相似文献   

Polygonal deformation bands     

《Journal of Structural Geology》2015

We report for the first time the occurrence of polygonal faults in sandstone, which is compelling given that layer-bound polygonal fault systems have been observed so far only in fine-grained sediments such as clay and chalk. The polygonal faults are shear deformation bands that developed under shallow burial conditions via strain hardening in dm-wide zones. The edges of the polygons are 1–5 m long. The shear deformation bands are organized as conjugate faults along each edge of the polygon and form characteristic horst-like structures. The individual deformation bands have slip magnitudes ranging from a few mm to 1.5 cm; the cumulative average slip magnitude in a zone is up to 10 cm. The deformation bands heaves, in aggregate form, accommodate a small isotropic horizontal extension (strain <0.005). The individual shear deformation bands show abutting T-junctions, veering, curving, and merging where they mechanically interact. Crosscutting relationships are rare. The interactions of the deformation bands are similar to those of mode I opening fractures. The documented fault networks have important implications for evaluating the geometry of km-scale polygonal fault systems in the subsurface, top seal integrity, as well as constraining paleo-tectonic stress regimes.  相似文献